Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 42, Pages 5124-5126Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31587d
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Funding
- NSFC [21072044]
- Excellent Youth Foundation of Henan Scientific Committee [114100510003]
- International Cooperation Foundation of Henan Province [104300510062]
- NUS ARF [R-143-000-461-112]
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A bicyclic guanidine-catalyzed Michael addition of 3-benzyl substituted oxindoles to N-maleimides has been developed to produce oxindole derivatives with a quaternary carbon chiral center at the 3-position in excellent yields and enantio- and diastereoselectivities. This is the first incorporation of N-benzylic alpha-branched succinimides into 3,3-disubstituted oxindoles.
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