Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 36, Pages 4314-4316Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31186k
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Funding
- MEXT, Japan [20108010, 237500141]
- KOSEF/MEST, Korea [R31-2008-000-10010-0]
- Grants-in-Aid for Scientific Research [23750014, 20108010] Funding Source: KAKEN
- National Research Foundation of Korea [R31-2012-000-10010-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A supramolecular binding occurred between lithium ion encapsulated [60]fullerene (Li+ @C-60) and sulfonated tetraphenylporphyrins ([MTPPS](4-) M = H-2 and Zn) in a benzonitrile solution. Photoexcitation of Li+ @C-60/[MTPPS](4-) results in formation of a long-lived charge-separated state by photoinduced electron transfer.
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