4.7 Article

Discotic hexa-peri-hexabenzocoronenes with strong dipole: synthesis, self-assembly and dynamic studies

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 5, Pages 702-704

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16740e

Keywords

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Funding

  1. DFG [SPP 1355, SPP 1459]
  2. ESF [09-EuroGRAPHENE-FP-001]
  3. EU
  4. ERC [NANOGRAPH]
  5. Alexander von Humboldt Foundation

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Strong dipole moments have been built into two hexa-peri-hexabenzocoronene (HBC) derivatives (1 and 2) originating from the push-pull structure of the molecules with one electron-donating and one electron-withdrawing substituent. The influence of dipole moment on the self-assembly of HBCs in solution and in bulk has been investigated.

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