Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 3, Pages 455-457Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14508h
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- NSERC
- RFBR
- OGS
- CFI/OIT
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The imido-hydrido complex (ArN) Mo(H)(Cl)(PMe3)(3) catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)(2). The latter species easily undergoes chemoselective coupling with aldehydes R'C(O)H to yield imines RCH2N=C(H) R'.
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