4.7 Article

Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 11, Pages 3239-3241

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04645k

Keywords

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Funding

  1. CNRS
  2. Crunch (interregional organic chemistry network)
  3. Region Basse-Normandie
  4. ERDF
  5. COST ACTION [CM0802]

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A new and smooth approach towards alkynylphosphine derivatives is described. It relies on the unprecedented catalytic coupling of secondary phosphine boranes with alkynyl bromides using the CuI/1,10-phenanthroline couple.

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