Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 8, Pages 2411-2413Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04548a
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Funding
- CAS
- NFSC [20772144, 20825209, 20832008]
- KAUST
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A chloride ion-catalyzed generation of difluorocarbene from a relatively non-toxic and inexpensive precursor, Me3SiCF2Cl (1), under mild and neutral conditions leads to an efficient preparation of gem-difluorocyclopropenes and difluorocyclopropanes through [2 + 1] cycloaddition reactions with alkynes and alkenes, respectively.
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