4.7 Article

Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 33, Pages 9522-9524

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13431k

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Funding

  1. Spanish Ministry of Science and Innovation [MAT2010-15870]
  2. Dutch National Science Foundation (NWO-CW VENI)

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Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH2-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO2/CH4 separation selectivity increases with pressure, related to the flexibility of the filler.

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