4.7 Article

Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 19, Pages 5533-5535

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11352f

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Funding

  1. European Union [70026/08]
  2. St. Petersburg State University [12.37.132.2011]

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The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.

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