Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 379-381Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02736g
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Ynamides and ynol ethers undergo intermolecular gold-catalysed reaction with a nucleophilic oxidant to access metal-carbenoid reactivity patterns. A site-specific oxidation/ 1,2-insertion cascade is used for a general access to functionalised alpha,beta-unsaturated carboxylic acid derivatives and vinylogous carbimates.
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