Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 3, Pages 1048-1050Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03613g
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Funding
- State Basic Research Project of China [2009CB623507]
- National Natural Science Foundation of China [21003107]
- Fundamental Research Funds for the Central Universities [2010QNA3035]
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TS-1 crystals with controllable b-oriented length (sheet-like morphology, TS-1-S; chain-like morphology, TS-1-C) have been rationally synthesized from addition of organic additives (urea and fluorinated surfactant of FC-4) in the starting titanosilicate gels, and catalytic and adsorptive measurements show that TS-1-S samples are very active in Beckmann rearrangement of cyclohexanone oxime, whereas TS-1-C samples are selective in adsorption for para-xylene.
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