Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 41, Pages 11394-11410Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12754c
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Funding
- National Science Foundation [CHE-0132886, DMR-0907043]
- Petroleum Research Foundation [35751-G3]
- North Dakota EPSCoR
- North Dakota State University
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The application of fused-ring thieno[3,4-b]pyrazines in conjugated organic polymers has been found to be a powerful approach to the production of low band gap materials. While thieno[3,4-b]pyrazine-based materials date back to the early 1990s, significant advances in the preparation and scope of thieno[3,4-b]pyrazine-based materials have been reported in recent years, primarily in response to the increasing demand for reduced band gap materials in photovoltaic devices. In this review, we provide an overview of thieno[3,4-b]pyrazines and their application to conjugated materials, highlighting in particular the recent advances in the breadth of thieno[3,4-b]pyrazine building blocks and the promise of tuning materials to achieve optimal properties for specific applications.
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