Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 13, Pages 3918-3920Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04697c
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Funding
- NSF-DMR [0907175, 0846958]
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A tin(II) tungstosilicate derivative K11H[Sn-4(SiW9O34)(2)]center dot 25H(2)O with four sandwiched Sn2+ cations was prepared by reaction of SnCl2, KCl and Na-10[alpha-SiW9O34]center dot xH(2)O. Visible-light photocatalytic H-2 evolution activity was observed with Pt nanoparticles as co-catalyst and methanol as sacrificial agent.
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