4.7 Article

Top-down fabrication of crystalline metal-organic framework nanosheets

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 29, Pages 8436-8438

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12510a

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Funding

  1. AIST
  2. Kobe University
  3. JSPS
  4. Grants-in-Aid for Scientific Research [10J01754] Funding Source: KAKEN

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Crystalline metal-organic framework (MOF) nanosheets have been fabricated via top-down delamination from bulk crystals of a layered MOF, {Zn(TPA)(H(2)O)center dot DMF}(n) (MOF-2), and characterized by Tyndall scattering, scanning electron microscopy and atomic force microscopy measurements. The delaminated MOF-2 nanosheets exhibit remarkable amine intercalation property and reversible amine exchangeability.

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