4.7 Article

Photomechanical bending of salicylideneaniline crystals

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 41, Pages 11423-11425

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14288g

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Funding

  1. MEXT, Japan

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Platelike microcrystals of N-3,5-di-tert-butylsalicylidene-3-nitroaniline repeatedly bend and straighten upon alternate irradiation with UV and visible light. The mechanism of bending was elucidated by X-ray crystallographic analyses before and after photoirradiation.

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