Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7821-7823Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12306h
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Funding
- National Natural Science Foundation of China [20732003, 21021001]
- Basic Research Program of China (973 Program) [2011CB808600]
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An efficient yttrium( III)- catalyzed highly enantioselective Friedel-Crafts alkylation of beta-trichloro(trifluoro)methyl aryl enones is described. The reaction delivered a series of functionalized indoles with a chiral tertiary carbon center bearing a trichloro(trifluoro) methyl group in excellent results (up to 96% ee and 99% yield) under mild conditions.
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