4.7 Article

Stability improvement of Cu-3(BTC)(2) metal-organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 28, Pages 8037-8039

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12341f

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Funding

  1. Flemish FWO
  2. FWO-Vlaanderen
  3. Flemish Government

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Cu-3(BTC)(2) with an incorporated Keggin polyoxometalate was demonstrated to be stable under steaming conditions up to 483 K, while the isostructural HKUST-1 degrades and transforms into [Cu2OH(BTC)(H2O)](n)center dot 2nH(2)O from 343 K onwards.

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