4.7 Article

Gold catalyzes the Sonogashira coupling reaction without the requirement of palladium impurities

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 5, Pages 1446-1448

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04564k

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Funding

  1. Consolider-Ingenio 2010 (project MULTICAT)
  2. Spanish MICINN [MAT2006-14274-C02-01-02]

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By a combination of kinetic and theoretical studies it is concluded that gold is intrinsically active to perform the Sonogashira coupling reaction between phenylacetylene and iodobenzene. The presence of Pd impurities is not mandatory for catalyst activity.

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