4.7 Article

Me-2-NHC based robust Ir catalyst for efficient water oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 9, Pages 2712-2714

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05108j

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Funding

  1. Netherlands' Organization for Scientific Research (NWO-CW, VENI) [700.59.410]

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Me-2-NHC proved to be a valuable ligand in iridium catalyzed water oxidation reactions, both when carried out electrochemically as well as upon oxidation with cerium ammonium nitrate. Mechanistic data suggest that water oxidation occurs efficiently at a well defined iridium species via a mononuclear pathway.

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