4.7 Article

A chiral metal-organic framework for sequential asymmetric catalysis

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 29, Pages 8256-8258

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12701b

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Funding

  1. NSF [CHE-0809776]

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A chiral metal-organic framework (MOF) of the lcy topology was constructed from the Mn-Salen derived dicarboxylic acid and the [Zn(4)(mu(4)-O)(O(2)CR)(6)] secondary building unit, and used in highly regio- and stereo-selective sequential alkene epoxidation/epoxide ring-opening reactions.

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