Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 14, Pages 4249-4251Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05522k
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The pH-dependent electrochemical behavior for a Co(II) complex, [Co(Py5)(OH2)](ClO4)(2) (1; Py5=2,6-(bis(bis-2-pyridyl)methoxymethane) pyridine), indicates consecutive (proton-coupled) oxidation steps furnish a Co-IV species that catalyzes the oxidation of water in basic media.
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