Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 5, Pages 1455-1457Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04807k
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Funding
- National Natural Science Foundation of China (NSFC) [21074064]
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An ATRA based strategy to synthesize vinyl copolymers with monomer-level sequence control is proposed. In each cycle, one allyl alcohol is added to the ATRP chain end, and then the hydroxymethyl residue is oxidized to carboxylic acid and a side group is introduced via esterification, making the new chain end active for the next cycle.
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