4.7 Article

Remarkably reactive dihydroindoloindoles via palladium-catalysed dearomatisation

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 12, Pages 3649-3651

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05033d

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Funding

  1. EPSRC [EP/E059376/1]
  2. AZ
  3. Engineering and Physical Sciences Research Council [EP/E059376/1] Funding Source: researchfish

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Palladium-catalysed dearomatisation reactions allow access to a previously unknown class of indoloindole heterocycle: 5,10b-dihydroindolo[2,3-b]indoles. The highly reactive nature of these compounds is demonstrated by their facile reactions with water and with hydride, alkyl, aryl and allyl-based organometallic nucleophiles.

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