4.7 Article

When Cu4I4 cubane meets Cu-3(pyrazolate)(3) triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 46, Pages 12441-12443

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14303d

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Funding

  1. National Basic Research Program of China (973 Program) [2012CB821700]
  2. National Natural Science Foundation for Distinguished Young Scholars of China [20825102]
  3. National Natural Science Foundation of China [20771072]

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A supramolecular dual emissive system incorporating two classical copper(I)-cluster-based luminophores, namely, Cu4I4 and Cu(3)Pz(3) (Pz = pyrazolate), is reported. The targeted luminescent coordination polymer exhibits reversible thermochromism spanning from green to orange-red.

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