4.7 Article

pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 48, Pages 12765-12767

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14799d

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Funding

  1. Spanish Ministerio de Ciencia e Innovacion [CTQ2009-12111]
  2. Junta de Castilla y Leon [VA070A08, GR Excelencia 125]
  3. MEC-FPU
  4. Ramon y Cajal contract

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Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.

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