4.7 Article

Porous cobalt(II)-imidazolate supramolecular isomeric frameworks with selective gas sorption property

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 17, Pages 4902-4904

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10899a

Keywords

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Funding

  1. National Natural Science Foundation of China [20731004, 21021062]
  2. National Basic Research Program of China [2007CB925103, 2010CB923303]

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Two porous supramolecular isomeric frameworks show unique sorption properties, one with temperature dependent stepwise and hysteretic selective sorption of CO2 while the other one shows gas uptake capacity for CO2, N-2, H-2 and CH4 at low temperature and selective sorption of CO2 over N-2 around room temperature.

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