4.7 Article

Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L=1,4-di(1H-imidazol-4-yl)benzene]

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 2, Pages 752-754

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04085a

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Funding

  1. National Natural Science Foundation of China [20731004, 20721002]
  2. National Basic Research Program of China [2007CB925103, 2010CB923303]

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A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H2L) and CuCl2 center dot 2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L2-, and shows temperature dependent selective gas sorption properties.

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