Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 493-495Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01769h
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Funding
- National Natural Science Foundation of China [20732006, 20821002, 20972177]
- National Basic Research Program of China (973 Program) [2009CB825300]
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A tandem NHC-catalyzed aza-benzoin/Michael reaction has been developed as a method to efficiently produce dihydroindenones and pyrrolidinone-containing tricycles. The novel reaction pattern involves tert-butyl aryl(tosyl)methylcarbamates reacting as both electrophile and nucleophile on the same carbon.
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