Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 17, Pages 5040-5042Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10827a
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Funding
- Boston University
- NIGMS [P50-GM067041]
- NSF [CHE-0619339, CHE-0443618]
- Vertex
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [P50GM067041] Funding Source: NIH RePORTER
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Herein we report an advancement in the application of visible light photoredox catalysts in the oxidation of electron-rich arenes resulting in the selective deprotection of para-methoxybenzyl (PMB) ethers. This method is highlighted by excellent functional group tolerance, protecting group orthogonality, mild reaction conditions and avoidance of stoichiometric redox byproducts.
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