Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 45, Pages 12313-12315Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15671c
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Funding
- Spanish MICINN [CTQ2008-00136/BQU]
- EJ/GV [IT328-10]
- UPV/EHU
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We have developed a highly efficient procedure for carrying out the catalytic enantioselective (3+2) cycloaddition between enals and stable azomethine ylides such as isoquinolinium and phthalizinium methylides. Under the optimized reaction conditions highly substituted chiral pyrroloisoquinolines and pyrrolophthalazines have been obtained in high yields and excellent diastereo- and enantioselectivities.
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