Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 36, Pages 10034-10036Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13596a
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- U. S. Department of Energy [DE-FG02-03ER15393]
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A method for radical coupling of porphyrins using copper(II) salts as one-electron oxidants was developed. A Zn(II)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.
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