4.7 Article

Regio- and stereoselective copper-catalyzed beta-borylation of allenoates by a preactivated diboron

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 424-426

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02270e

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Funding

  1. Virginia Tech Department of Chemistry
  2. Thomas F. Jeffress and Kate Miller Jeffress Memorial Trust

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A mild and efficient copper-catalyzed borylation of electron deficient allenoates using an sp(2)-sp(3) mixed hybridized diboron regioselectively installs a boron moiety on the beta-position with exclusive (Z)-double bond geometry.

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