4.7 Article

A bright tetranuclear iridium(III) complex

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2799-2801

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05029f

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Funding

  1. Solvay S. A.

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A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.

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