4.7 Article

Synthesis of a polythieno[3,4-b]thiophene derivative with a low-lying HOMO level and its application in polymer solar cells

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8850-8852

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12643a

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Funding

  1. NSFC [20874106, 20821120293, 50633050, 20721061]
  2. National Science Foundation [CHE-0822573]

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A planar benzodithiophene with lower HOMO was copolymerized with the thieno[3,4-b]thiophene unit to obtain a new low band gap polymer of PBDPTT-C, which exhibited a higher open-circuit voltage (V-oc) of 0.8 V and a promising efficiency of 5.2%.

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