Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 25, Pages 7152-7154Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12162f
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Funding
- University of Bayreuth
- Deutsche Forschungsgemeinschaft [WE 3546_4-1]
- Fonds der Chemischen Industrie
- IAP-VI [P6/17]
- INANOMAT
- FNRS [FRFC 2.4508.08]
- ARC-Academie Louvain
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A novel iron(II) mononuclear spin transition complex [FeL(py)(2)] displays an abrupt spin transition around 225 K accompanied by a very wide thermal hysteresis loop (similar to 50 K) that spreads out over 100 K. Crystal structure analysis in both low-spin and high-spin states reveals a lipid layer-like arrangement of the complex molecules and provides insights into the spin switching mechanism.
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