4.7 Article

Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 406-408

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02742a

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Funding

  1. US National Science Foundation [CHE-0954710]

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The m-terphenyl isocyanides CNArMes2 and CNArDipp2 support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNArDipp2, a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.

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