Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 43, Pages 11855-11857Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14682c
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Funding
- National Science Foundation [0618242]
- Ministry of Education, Science and Technology [2011-0019531]
- Welch Foundation [F-1738]
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PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.
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