4.7 Article

High capacity gas storage by a 4,8-connected metal-organic polyhedral framework

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 15, Pages 4487-4489

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10378d

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Funding

  1. EPSRC
  2. University of Nottingham
  3. ERC
  4. Royal Society Leverhulme Trust
  5. EPSRC [EP/I011870/1, EP/I020942/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/I011870/1, EP/I020942/1, EP/C528964/1] Funding Source: researchfish

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The polyhedral complex [Cu(4)L(H(2)O)(4)]solv (NOTT-140) shows a 4,8-connected structure of rare scu topology comprising octahedral and cuboctahedral cages; desolvated NOTT-140a shows a total CO(2) uptake of 314.6 cm(3) (STP) cm(-3) at 20 bar, 293 K, and a total H(2) uptake of 6.0 wt% at 20 bar, 77 K.

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