Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 30, Pages 8682-8684Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13424h
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Funding
- National Natural Science Foundation of China [20902084]
- Science and Technology Office in Zhejiang Province [2010R10016]
- Program for Changjiang Scholars and Innovative Research Team in Chinese Universities [IRT0980]
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Described herein is a Pd-catalyzed haloallylation of aromatic ynol ethers and allyl chlorides, allowing facile access to (1E)-alpha-chloroenol ethers in a highly regio- and stereoselective manner. The synthetic utility of this method is demonstrated well by the synthesis of the stereodefined multisubstituted enol ethers and alpha-allylated carbonyl compounds.
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