4.7 Article

One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Bronsted-Lewis-surfactant-combined heteropolyacid catalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 7, Pages 2176-2178

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04444j

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Funding

  1. National Natural Science Foundation of China [20871026]
  2. National Innovation Experiment Program for Undergraduates [091020036]

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A Bronsted-Lewis-surfactant-combined heteropolyacid (HPA) Cr[(DS)H2PW12O40](3) has been synthesized, and is used as a heterogeneous catalyst for the conversion of cellulose to 5-hydroxymethylfurfural in one pot within 2 h at 150 degrees C with 77.1% conversion and 52.7% yield. This micellar HPA catalyst shows stability and can be recycled by simple separation process.

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