Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 39, Pages 11131-11133Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14641f
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Species R2PCH2AlMe2 (R = Me, Ph) are stable Lewis adducts but still react with CO2 both in solution and in the solid state. The CO2 adducts undergo a rearrangement unprecedented for ambiphilic molecules to form aluminium carboxylates. A new spirocyclic compound was also obtained by double Lewis pair activation of CO2.
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