4.7 Article

High reaction activity of nitrogen-doped carbon nanotubes toward the electrooxidation of nitric oxide

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 25, Pages 7137-7139

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11611h

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Funding

  1. National Basic Research Program of China [2010CB732400]
  2. National Natural Science Foundation of China [21035002, 20875013]
  3. Natural Science Foundation of Jiangsu province [BK2010059]

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Carbon nanotubes doped with N (NCNTs) enable 1.5 times faster electron-transfer kinetics for the oxidation of NO compared to pristine carbon nanotubes (CNTs), which may be due to the low adsorption energy for a NO on pyridinic NCNT(5,5) allowing NO to lose electrons readily and facilitate the following oxidation to nitrate.

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