4.7 Article

Redox control of a polymerization catalyst by changing the oxidation state of the metal center

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 35, Pages 9897-9899

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13117f

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Funding

  1. UCLA, DOE [ER15984]
  2. Sloan Foundation
  3. University of Erlangen-Nuremburg
  4. DFG
  5. Bavarian California Technology Center
  6. DOE [DE-AC02-06CH11357]
  7. CINES [c2011086494]

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The activity of cerium alkoxide complexes supported by a Schiff base ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The rate of L-lactide polymerization was modified by switching in situ between the cerium(III) and cerium(IV) species.

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