Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2943-2945Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04496b
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Funding
- National Research Foundation [R01-2008-000-20332-0, NRF-20090085824]
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The copper-catalyzed addition of bis(pinacolato) diboron to internal alkynes in the presence of methanol generates alkenylboron compounds with high levels of regio- and stereoselectivities. The catalytic efficiency is increased by using monodentate phosphine ligands, especially P(p-tolyl)(3) and a range of internal alkynes was borylated in good yields.
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