4.7 Article

Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)(3)

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 9, Pages 2682-2684

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05294a

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Funding

  1. EPSRC
  2. Cambridge University
  3. Leverhulme Trust
  4. EPSRC [EP/D077400/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/D077400/1] Funding Source: researchfish

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The catalytic dehydrocoupling reaction of Me2NHBH3 with Al(NMe2)(3) gives the dimer [Me2NBH2](2) and the chain [(Me2N)(2)BH], involving the thermally-stable Al-III hydride catalyst [{(Me2N)(2)BH2}(2)AlH].

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