4.7 Article

Highly chemoselective hydrogenation of crotonaldehyde over Ag-In/SBA-15 fabricated by a modified two solvents strategy

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 21, Pages 6168-6170

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11013f

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Funding

  1. NSF of China [20803011, 21073043]
  2. Shanghai Science and Technology Committee [10JC1401800, 08DZ2270500]
  3. Program of New Century Excellent Talents in Universities [NCET-08-0126]

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In the challenging crotonaldehyde hydrogenation to crotyl alcohol, an Ag-In/SBA-15 catalyst fabricated by a modified two solvents'' strategy shows an unprecedentedly high yield of 86% at a selectivity of 87%, which exceeds the best results on Pt-, Au- and other Ag-based heterogeneous catalysts reported so far.

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