4.7 Article

A multipurpose gold(I) precatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 17, Pages 4893-4895

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10293a

Keywords

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Funding

  1. MICINN [CTQ2010-16088/BQU, CTQ2008-00947/BQU, CSD2006-0003]
  2. AGAUR [2009SGR47, 2009SGR623]
  3. ICIQ Foundation

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[Au(tmbn)(2)](SbF6) is the first gold(I) complex supported by two nitrile ligands that is indefinitely stable at room temperature. This is a highly versatile precatalyst that can be used for the preparation of active and robust solid-supported gold(I) catalysts.

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