Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 6, Pages 1716-1718Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04366d
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Funding
- University of Padova
- MIUR [20085M27SS]
- Fondazione Cariparo
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The oxygen evolving catalyst [Ru-4(mu-OH)(2)(mu-O)(4)(H2O)(4)-(gamma-SiW10O36)(2)](10-) effects H2O2 dismutation at rates (k = 36.8 +/- 1.4 M-1 s(-1)), one/two order of magnitude higher compared to related tetra-substituted Cu, Fe, Mn, Ni and even Co polyoxometalates, thus providing localised oxygen gas bursts to power nano-propulsion of composite materials.
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