4.7 Article

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 18, Pages 5289-5291

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10953g

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Funding

  1. CAS
  2. State Key Laboratory of Fine Chemicals [KF1008]

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We present a PdCl2-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and atom-efficient functionalization of heteroarenes.

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