Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 18, Pages 5289-5291Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10953g
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- CAS
- State Key Laboratory of Fine Chemicals [KF1008]
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We present a PdCl2-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and atom-efficient functionalization of heteroarenes.
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