4.7 Article

Au(PPh3)OPOF2-catalyzed intramolecular [4+2] cycloaddition reaction of dienynes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 23, Pages 6719-6721

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11127b

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Funding

  1. National Research Foundation of Korea (NRF) [2010-0029663]
  2. Ministry of Education, Science and Technology [R11-2005-065]

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Solvolysis of Au(PPh3)PF6 afforded Au(PPh3)OPOF2 which is an effective catalyst in the intramolecular [4+2] cycloaddition of unactivated dienynes bearing a terminal alkyne.

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