Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 37, Pages 10227-10229Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12222c
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Funding
- National Research Foundation (NRF) via National Research Laboratory [R0A-2008-000-20041-0]
- National Research Foundation (NRF) via Converging Research Center [2009-0082276]
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Among the porphyrin molecules with different metal insertion sites and functional ligands, Zn-porphyrin most efficiently regenerates NADH through photo-induced electron transfer in the presence of [Cp*Rh(bpy)H(2)O](2+), a rhodium-based electron mediator. Photochemical regeneration of NADH by Zn-porphyrin is successfully coupled with redox enzymatic synthesis under dark state conditions.
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